(c) radius of Br - (196) > radius of Br (114) (b) radius of Cl - (181) > radius of Cl (99) (a) radius of F - (131) > radius of F (71) the radius of the anion is always greater than the radius of the atom?.We can write a chemical equation to represent this for any group 17 element (X) as shown below (B) Comparison of Atomic and Ionic Radius of Group 17 (VIIA, halogen) Elementsġ electron (e -) can be added to the valence shell of the atoms of group 17 elements to form an anion with a charge of -1 (X -) The same nuclear positive charge is now acting on fewer negatively charged electrons so these electrons are drawn in closer towards to the nucleus and the radius of the cation will be less than the radius of the atom. However, if an electron is removed from a Group 1 atom it is removed from the highest energy level (valence shell), so this effectively reduces the number of occupied energy levels (or electron shells). (e) Cs has 6 electron shells occupied, Li + has 6 - 1 = 5 electron shells occupiedĪs you go down the group from top to bottom, the ionic radius of each cation increases, just as it does for the radius of each atom because an energy level (electron shell) is being added to each successive atom (or ion). (d) Rb has 5 electron shells occupied, Rb + has 5 - 1 = 4 electron shells occupied (c) K has 4 electron shells occupied, K + has 4 - 1 = 3 electron shells occupied (b) Na has 3 electron shells occupied, Na + has 3 - 1 = 2 electron shells occupied (a) Li has 2 electron shells occupied, Li + has 2 - 1 = 1 electron shell occupied the cation has 1 less occupied energy levels (electron shells) ?.(e) ionic radius Cs + (170) < atomic radius Cs (225) (d) ionic radius Rb + (149) < atomic radius Rb (211) (c) ionic radius K + (138) <</a> atomic radius K (196) (b) ionic radius Na + (102) < atomic radius Na (154) (a) ionic radius Li + (74) < atomic radius Li (134) the cationic radius of an element is always less than its atomic radius?.We can wrote a chemical equation to represent this for any group 1 element (M) as shown below
(A) Comparison of Atomic and Ionic Radius of Group 1 (IA, alkali metals) ElementsĪtoms of group 1 elements (M) lose 1 electron (e -) from their valence shell of electrons to form a cation with a charge of +1 (M +) Group 17 elements form anions with a charge of -1 Group 1 elements form cations with a charge of +1 Let's compare the radius of some elements' atoms with their respective ions. Down a Group of the Periodic Table from top to bottom, comparing ions with a similar charge, the ionic radius increases as the number of completed energy levels increases.Anions are larger than their respective atoms as electrons are added to the highest energy level (valence shell) the repulsion between the negatively charged electrons increases the ionic radius.Cations are smaller than their respective atoms as electrons are removed from the highest energy level (valence shell) while the positive nuclear charge remains the same thereby increasing the attraction between the remaining electrons and the nucleus resulting in a reduction in the size of the radius of the cation.Use the data given in the table below to find patterns (trends) in (B) Trends in the Atomic Radius of Elements in Period 3 atomic radius of the elements decreases from 134 pm to 69 pm across the period from left to rightĪtomic radius generally decreases across Period 2 from left to right as the nuclear charge increases.charge on the nucleus (nuclear charge) increases from +3 to +10 across the period from left to right.number of occupied energy levels (electron shells) remains the same (2 occupied electron shells) across the period.number
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If you're a solitaire enthusiast, you're in the right place. ![]() To the best of my recollection, Jimmy was a really cool guy - and, honestly, it wasn’t his fault and it wasn’t my fault, because I was ready to play. “We didn’t really have any of the songs ready to go when we went in there with Jimmy. “The truth is, Rod and Dave were struggling with writing the songs this time around,” Roger admits. However, things just didn’t work out, as evidenced by the band and their newly minted producer butting heads about three songs into the process. But when Dave was performing - whether he was singing or playing his guitar - he lit up like a downtown Christmas tree.” (Lonesome Dave passed away at age 56 in 2000.) As the Night Shift rehearsals commenced in the British band’s adopted homebase of Long Island, New York - first in the backroom of a local pork store before moving to friendlier recording confines - Jimmy Iovine, a Bearsville favorite who at that point had engineered albums from John Lennon and Bruce Springsteen, was initially slotted as the album’s producer. When he wasn’t singing, he was very quiet. ![]() Dave was always somewhat of a reluctant hero, but he was one of the best. Dave changed some of the lyrics, the phrasing, and the melody. That song was particularly tricky to get the groove and tempo on, but Craig and I sat down together and worked it out. “Lonesome Dave had knowledge of all things music, whether it be blues, jazz, country, rock & roll, or any other genre. “The idea for covering that song came from Lonesome Dave - of course,” confirms Roger. “Whether you’re sitting behind your desk or you’re on the line putting wheels onto cars, that title is what grabbed people right away - and the music delivers on it.” Special note must be given to the band’s uplifting, funky cover of “Take Me to the River,” a version of Reverend Al Green’s 1974 soul classic so original and so musically compelling that it remains in the band’s setlist to this day. (Eagle-eyed fans will also note the acoustic-driven “New Place to Call Home,” an unfinished song unearthed from the original sessions that appears as a bonus track on the currently out-of-print 2006 Wounded Bird Records Night Shift CD reissue, among other places.) Why does Night Shift continue to hold such sway with Foghat fans both new and old alike, 45 years after its release? It’s really quite simple, according to Foghat’s founding drummer, Roger Earl: “This is a working man’s band, and the album has a working man’s title,” he observes. In addition to the aforementioned album-bookend tracks “Drivin’ Wheel” and “I’ll Be Standing By,” the gritty gear-shifting movements of “Don’t Run Me Down,” the keep pushin’ on thrust of “Burnin’ the Midnight Oil” (which also happens to be the album’s most played track on Spotify), the signature sizzle of “Night Shift,” the good-time jammin’ of “Hot Shot Love,” and the funkified recasting of “Take Me to the River” all serve to reinforce the in-studio mind meld between lead vocalist/guitarist Lonesome Dave Peverett, slide guitar maestro Rod Price, then-newly appointed bassist Craig MacGregor, and drummer/percussionist extraordinaire Roger Earl. The band’s eagerly anticipated follow up to September 1975’s uber-successful million-selling Fool for the City, Night Shift continued to creatively expand upon the special four-man groove that made Foghat a household name. Hot 100 singles chart, while the heartfelt, strings-drenched album-closing ballad, “I’ll Be Standing By,” made it to No. (It’s high time for an updated sales recertification, we say!) The hard-charging opening track “Drivin’ Wheel” reached No. 36 on the Billboard Top 200 Albums chart and has since been certified as Gold by the RIAA, signifying over 500,000 copies sold. Produced by Dan Hartman - the acclaimed bassist for Edgar Winter Group and the solo artist behind the 1984 Top 10 single “I Can Dream About You” - Night Shift reached No. Night Shift, Foghat’s sixth studio album, was released 45 years ago by Bearsville Records on November 18, 1976. Episode #1 by Mike Mettler, official FoghatStorian 11-23-21 Next week, I’ll post the less extreme ending of Manuel Castillo’s Only Extreme 3 that Gordon Fick sent me, and we’ll get on with the Only Extreme review. I don’t expect any more naughty 5-stars like this one, disturbing the Sunday morning peace. Sudoku is a number-placing puzzle based on a 9x9 grid with several given numbers. It seems to require a one-term Sue de Coq, but one that could have been spotted in line marking. Although BJ readers may question that with the 9/24/17 5-star I sat down to yesterday. Ouch! The unintended multiple solutions explain the sudden jump in difficulty from basic to extreme. Blue, red, and tan accompany yellow, and an independent extended rectangle emerges, for four more solutions.įinally, aqua/orange/blue trials add two solutions, and aqua/orange/green provide the newspaper’s, the double sized. The multiple solution justifies going back to yellow in the red trial to pick up the rectangle multiple. In the trial, yellow would generate a two- solution rectangle.ĭiscarding yellow, evidence of multiple solution appears as aqua and tan generate a four line extended rectangle in the East tower, while aqua and pink bring a third solution. No further conflicts, so I start a red trial. The object is to fill all empty squares so that the numbers 1 to 9 appear exactly once in each row, column and 3x3 box, and the sum of the numbers in each area is equal to the clue in the area’s top-left corner. I added pink/tan and aqua/yellow clusters. Each puzzle consists of a 9x9 Sudoku grid containing areas surrounded by gray or dotted lines. green conflict in r7 means blue or orange or both are true. Nothing worked for me until this very indecisive coloring trap and possible bridge prompted more clusters. Huge brain-bashing Mega Sudoku puzzles, also known as Monster Sudoku, are offered for iPad only. The difficult line marking, and just getting through basic, were signs that this was not my typical Sunday treat.įortunately, I got it transcribed to the template before the newsprint version became unreadable. Play six different Sudoku variations in a single app Start with classic Sudoku grids and advance to Diagonal Sudoku, Irregular Sudoku and OddEven Sudoku - each with a different look and a unique twist of brain challenging logic. You get another demonstration of coloring as a humanly practical way to deal with multiple solutions. After no other advanced progress, a four cluster coloring proves 10 solutions. This one breaks tradition by surviving Sysudoku basic, and with a heavy line marking. 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Our Senior Citizen Programs are available to seniors who need assistance – we offer specialized billing cycles, discounts, and more. Historical Electricity Rates: Price Per kWh Average Bill 0.162 /kWh 0.094 /kWh. ![]() If you have previously used a different nickname under IRC, you may use that instead. Looking for help with your story or want to assist authors? Review our rules and then come on in! Alternate hosting available at: RoyalRoad Community Interaction Discord Channel If you have written a series, please link the previous and next entries in the series in the main body of text. Misc-For relevant submissions that do not fit into one of the above categories.Meta-For a post about the sub itself or stories from HFY.Also note, that videos in general may be subject to removal if people complain that their relevance is dubious. ![]()
![]() ĭuring 1903, Murdoch finally reached the stormy and glamorous North Atlantic run as Second Officer of the new liner Arabic. Hannah would see Murdoch for the last time when he witnessed the testing of lifeboats before Titanic departed from Southampton on 10 April 1912. Captain Hannah came from a family of seafarers with their roots in Kircudbrightshire like Murdoch, and was Assistant Marine Superintendent for the White Star Line at Southampton. The marriage register entry was witnessed by Captain William James Hannah and his wife and the addresses given by the bride and groom suggest they were lodging with the Hannahs. They began to correspond regularly on 2 September 1907 they were wed in Southampton at St Denys Church. In 1903, Murdoch met a 29-year-old New Zealand school teacher named Ada Florence Banks en route to England on either the Runic or the Medic. From 1900 to 1912, Murdoch gradually progressed from Second Officer to First Officer and quickly rose to the rank of officer, serving on a successive number of White Star Line vessels, Medic (1900, along with Charles Lightoller, Titanic 's second officer), Runic (1901–1903), Arabic (1903), Celtic (1904), Germanic (1904), Oceanic (1905), Cedric (1906), Adriatic (1907–1911) and Olympic (1911–1912). Smith, all as seen on the OlympicĪn officer of the Royal Naval Reserve, he was employed by the White Star Line in 1900. Murdoch in his 30s From left to right: Murdoch, Chief Officer Joseph Evans, Fourth Officer David Alexander and Captain Edward J. steel four-masted 2,534-ton barque Lydgate, that traded from New York to Shanghai. From 1897 to 1899, he was First Officer aboard the J. ![]() Murdoch gained his Extra Master's Certificate at Liverpool in 1896, at age 23. Cuthbert, which sank in a hurricane off Uruguay in 1897. From May 1895, he was First Mate on the St. He served his apprenticeship aboard the Charles Cosworth of Liverpool, trading to the west coast of South America. Finishing schooling, he followed in the family seafaring tradition and was apprenticed for five years to William Joyce & Coy, Liverpool, but after four years (and four voyages) he was so competent that he passed his second mate's Certificate on his first attempt. Murdoch was educated first at the old Primary School in High Street, and then at the Dalbeattie High School in Alpine Street until he gained his diploma in 1887. The Murdochs were a long and notable line of Scottish seafarers his father and grandfather were both sea captains as were four of his grandfather's brothers. ![]() Murdoch was born in Dalbeattie in Kirkcudbrightshire (now Dumfries and Galloway), Scotland, the fourth son of Captain Samuel Murdoch, a master mariner, and Jane Muirhead, six of whose children survived infancy. He was the officer in charge on the bridge when the ship collided with an iceberg, and was one of the more than 1,500 people who died when the ship sank. William McMaster Murdoch, RNR (28 February 1873 – 15 April 1912) was a Scottish sailor, who was the first officer on the RMS Titanic. For more guidance, see Wikipedia:Translation.You should also add the template to the talk page.A model attribution edit summary is Content in this edit is translated from the existing French Wikipedia article at ] see its history for attribution. You must provide copyright attribution in the edit summary accompanying your translation by providing an interlanguage link to the source of your translation.If possible, verify the text with references provided in the foreign-language article. Do not translate text that appears unreliable or low-quality.Consider adding a topic to this template: there are already 5,790 articles in the main category, and specifying |topic= will aid in categorization.Machine translation, like DeepL or Google Translate, is a useful starting point for translations, but translators must revise errors as necessary and confirm that the translation is accurate, rather than simply copy-pasting machine-translated text into the English Wikipedia.View a machine-translated version of the French article. There are also several websites with tools for creating pixel art. You probably already have MS Paint on your computer, but GIMP has so much more functionality, and Paint.NET is quite user-friendly. You will need an image editor such as Paint.NET or GIMP to edit or create. png format (example: yournewlogo.png) in multiples of 16 pixels square (example: 16x16, 32x32, 64圆4). Image files you may be familiar with include.You probably already have a basic text editor on your computer, but there are many advantages to using other ones instead. You will need a text editor such as Notepad++, Vim, or Emacs to read or create JSON files. ![]()
![]() The central location in the heart of Beverly Hills and the 90210 zip code make it a highly-coveted address. The units are 2-5 bedrooms and all have unique footprints. The luxurious floor plans offer custom finishes and designer touches throughout. The Montage Residences sit atop the top 3 floors of the 5-star Montage Hotel in Beverly Hills. Montage Residences Beverly Hills Condo Unit Square Feet:
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